Hi,
No, there is no JR Pass for Gran Class. Actually, there are comparatively few bullet trains with Gran Class seats. You could upgrade the seats from your pass, but the pass only covers the base fare, and the extra costs would be very high - the seat difference as well as the bullet train surcharge. You'd need to do it at the JR office before you ride each time, which would be a troublesome headache, or keep to a very strict schedule and do it for all the trains with Gran seats you plan to take ahead of time.
For the costs, look on Hyperdia. Under "More Options", be sure to uncheck the Nozomi box since you can't ride that train using the pass. Look under the Seat Fee drop down menu. If you don't see Gran Class, the train does not have it.
Good luck.